By Angelo Albini, Stefano Protti
This short discusses the formation of contemporary “green chemistry” as a contribution to sustainability and the old paths that result in the most important innovations of this self-discipline. inside of this highbrow framework, the ebook tackles the 12 rules of eco-friendly chemistry and the 12 rules of eco-friendly chemical engineering in addition to comparable monetary and administration matters; those proof are explored and reformulated in a concentrated set of paradigms. the most suitable choice of a version for quantitative evaluation (sufficiently particular to account for the numerous parameters concerned yet now not excessively distinct to inhibit functional use) is mentioned and examples of sensible purposes are presented.
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Extra resources for Paradigms in Green Chemistry and Technology
Example text
Due to the high pH value required, degradation of base sensitive substrates and products afforded several by-products, making the development of a cyanation reaction at neutral pH highly preferable. The enzymatic multistep process developed by Codexis has been successfully applied for the multiton scale production of 47. In this process the stability and activity of enzymes has been improved by DNA shuffling technology. Thus, biocatalytic reduction of ethyl-4-chloroacetoacetate has been carried out by means of a ketoreductase (KRED) in combination with glucose and NADP-dependent glucose dehydrogenase (GDH) for cofactor regeneration.
Due to the high pH value required, degradation of base sensitive substrates and products afforded several by-products, making the development of a cyanation reaction at neutral pH highly preferable. The enzymatic multistep process developed by Codexis has been successfully applied for the multiton scale production of 47. In this process the stability and activity of enzymes has been improved by DNA shuffling technology. Thus, biocatalytic reduction of ethyl-4-chloroacetoacetate has been carried out by means of a ketoreductase (KRED) in combination with glucose and NADP-dependent glucose dehydrogenase (GDH) for cofactor regeneration.
15) has been successful applied to the highly atom economic multicomponent synthesis of amidoalkyl naphthol derivatives 50 (the corresponding 1,3-amino-oxygenated moiety is largely present among a variety of natural compounds) under solvent-free reaction condition. 35) [73]. Carbonylation. The term carbonylation covers a large variety of reaction in which carbon monoxide is incorporated into a substrate by the addition of CO to a carbon based palladium complex in the presence of various nucleophiles.