By Ernest W. Colvin, J. E. Baldwin, A.D. Buckingham and S. Danishefsky (Auth.)

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Chem. Ber. 110, 852 (1977) 12 PETERSON, D. , J. org. Chem. 33, 780 (1968) 13 CAREY, F. A. and COURT, A. , J. org. Chem. 37, 939 (1972); CAREY, F. A. , J. org. Chem. 38, 2670 (1973) 14 WU, T. C , WITTENBERG, D. , J. org. Chem. 25, 596 (1960) 15 GILMAN, H. , J. organometal. Chem. 2, 44 (1964) 16 CORRIU, R. J. , MASSE, J. , J. organometal. Chem. 71, 93 (1975) 17 LAU, P. W. K. and CHAN, T. , Tetrahedron Lett. , EHLINGER, E. , 7. chem. Soc. chem. Communs 772 (1977) 19 CARTER, M. J. , J. chem. Soc.

And RATHKE, M. , Tetrahedron Lett. 709 (1978); J. org. Chem. 43, 1947 (1978) 41 HART, D. , CAIN, P. A. and EVANS, D. , J. Am. chem. Soc. 100, 1548 (1978) a-Metallated organosilanes 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 29 LUCAST, D. H. , Tetrahedron Lett. 1103 (1977) HUDRLIK, P. , PETERSON, D. , Synth. , Tetrahedron Lett. 4041 (1976) COREY, E. J. and BOGER, D. , Tetrahedron Lett. , FUNAKI, Κ. , Synthesis 746 (1978) COOKE, F. , J. chem. Soc. chem. , EHLINGER, E. , J. Am. chem.

Chem. Soc. Perkin 126 (1979) 37 EVANS, D. , TAKACS, J. M. and HURST, K. , J. Am. chem. Soc. , COLLINS, W. T. and HOWE, J. , J. Am. chem. Soc. 92,4544 (1970); REICH, H. J. and MURCIA, D. , J. Am. chem. Soc. 95, 3418 (1973) 39 KUSNEZOWA, I. , RÜHLMANN, K. , J. organometal. Chem. 47, 53 (1973) 40 COATES, R. , SANDEFUR, L. O. and SMILLIE, R. , J. Am. chem. Soc. 97, 1619 (1975) Chapter 6 Organohalogenosilanes and substitution at silicon Organohalogenosilanes are by far the most important intermediates in organosilicon chemistry, and their involvement via nucleophilic displacement reactions is displayed in almost every chapter of this book.

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