By E. H. Rodd, Martin F. Ansell
At a time while there are various professional experiences, monographs and reviews on hand, there's nonetheless an enormous position for a publication comparable to ``Rodd'' which provides a broader assurance of natural chemistry. One point of the price of this paintings is that it permits knowledgeable in a single box to determine speedy what's taking place in different fields of chemistry. however, a chemist searching for the best way right into a box of research will locate inside Rodd an overview of the $64000 points of that region of chemistry, including top references to different works to supply extra particular details.
Read Online or Download Rodd's Chemistry of Carbon Compounds Volume 4 Six-Membered Heterocyclic Compounds With a Single Nitrogen Atom in the Ring (Rodd's Chemistry of Carbon Compounds 2nd Edition) PDF
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Additional info for Rodd's Chemistry of Carbon Compounds Volume 4 Six-Membered Heterocyclic Compounds With a Single Nitrogen Atom in the Ring (Rodd's Chemistry of Carbon Compounds 2nd Edition)
Example text
34 (i) hv (ii) LiAIH 4 R 0 --B~ I F F Photolysis of aromatic media results Padwa, Chem. , Schiff's bases in strongly acidic cyclisation to 1977, 77, 37). phenanthridines Irradiation (A. I. , Izvestia, 1980, 1606). F F (C6F5)2C = NC6H 5 . ~. S. G. Amin, J. , 1976, 1_~3. F. W. Rees, Chem. , 1982, 520). 35 The IH-chemical below. , J. A. chem. Soc. Perkin II, 1979, 386). 17 Proton chemical shifts (6) for phenanthridine (ii) Phenanthridinium salts Ethidium bromide phenanthridinium agent and, (41), bromide, 3,4-diamine-5-ethy l-6-pheny I is of value together with propidium as a probe for characterising structure.
Methoxy and group, loss of a (I. Ninomiya 1723). of the follows tetrahydrophenanthridone. unsaturated chem. acylanilides electron the Soc. 4N- a, ~ - et Gl. 5]-migration of the o-substituent occurs mixture of the cis 197). the the the (I. Ninomiya substituent position, ortho to gives I, J. chem. , Irradation and trans octahydrophenanthridones J. trans- If the enamine bears an o- [1,5]-shift methanol yields through to the 6'-position. H h~ 0 N. ~, h~ N 0 Ph 0 Ph In the presence of a chiral dibasic acid, photocylisation of the unsaturated acylanilide yields an optically active phenanthridone; (T.
A. an Denny, an aniline the presence alternative J. with chem. Soc. of approach Perkin I, 1986, 1055). Diphenylamines carboxyl containing substituents can act as precursors necessarily v~a a of acridones, carbocation examples include the Praefcke and U. Schulze, other intermediate thiobenzoate Synthesis, (3 2) than though not and novel (J. Martens, 1976, 532) and K. the Schiff's base (33). ~~N~hS ~ o Me (32) ~ . , (M. N. Reed and V. Snieckus, 1982, 104, 5531). The particular this work lies in the regiospecific J.