By Saul Patai
Content:
Chapter 1 Synthesis of crown ethers and analogues (pages 1–57): Dale A. Laidler and J. Fraser Stoddart
Chapter 2 Crown ethers–complexes and selectivity (pages 59–156): Fritz Vogtle and Edwin Weber
Chapter three natural modifications mediated through macrocyclic multidentate ligands (pages 157–174): Charles L. Liotta
Chapter four Geometry of the ether, sulphide and hydroxyl teams and structural chemistry of macrocyclic and non?cyclic polyether compounds (pages 175–214): Israel Goldberg
Chapter five Stereodynamics of alcohols, ethers, thio ethers and comparable compounds (pages 215–278): C. Hackett Bushweller and Michael H. Gianni
Chapter 6 Chiroptical homes of alcohols, ethers, thio ethers and disulphides (pages 279–298): G. Gottarelli and B. Samori
Chapter 7 The mass spectra of ethers and sulphides (pages 299–325): Christian C. Van De Sande
Chapter eight The electrochemistry of ethers, hydroxyl teams and their sulphur analogues (pages 327–350): Tatsuya Shono
Chapter nine digital buildings and thermochemistry of phenols (pages 351–377): Jean Royer, man Bertholon, Robert Perrin, Roger Lamartine and Monique Perrin
Chapter 10 Syntheses and makes use of of isotopically labelled ethers and sulphides (pages 379–448): Mieczyslaw Zielinski
Chapter eleven Gas?phase thermal decompositions of easy alcohols, thiols and sulphides (pages 449–468): R. L. Failes, J. S. Shapiro and V. R. Stimson
Chapter 12 Oxidation and aid of alcohols and ethers (pages 469–538): Paul Muller
Chapter thirteen Oxidation and aid of sulphides (pages 539–608): Eric Block
Read or Download Ethers, Crown Ethers, Hydroxyl Groups and their Sulphur Analogues: Volume 1 (1981) PDF
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Additional resources for Ethers, Crown Ethers, Hydroxyl Groups and their Sulphur Analogues: Volume 1 (1981)
Sample text
Amer. Chem. ,98, 4018 (1976); S. S. Moore, T. L. Tarnowski, M. Newcomb and D. J. Cram, J. Amer. , 99, 6398 (1977); hl. Newcomb, S . S. Moore and D. J. Cram, J. Amer. Chem. , 99,6405 (1977). 100. M. A. McKervey and D. L. MuIholland,J. Chem. , 438 (1977). 101. S . J. Leigh and 1. 0. Sutherland, J . Chetn. Soc.. Chetn. , 414 (1975); L. C . Hodgkinson, S. J. Leigh and I . 0. Sutherland, J. CJ7em. , Chem. , 639, 640 (1976). 102. R. C. Helgeson, T. L. Tarnowski, J. M. Timko and D. J. Cram, J. Amer. Chern.
128, are also known9 7 * 9 a . e. A. In addition t o these investigations by Reinhoudt and his collabora t o r 3, ~ ~Cram and his associates9 have prepared numerous meta-xylyl-18-crown-6 derivatives with substituents at C(2) and C(5 1. Recently, phenolic crown ethers, such as 129, have been obtained' O 0 in greater than 90% yield by de-0-methylation (129) of the corresponding methyl ethers upon exposure t o anhydrous LiI in dry C5 HsN at looo for 10 h followed by acidification. The success of these deetherifications has been attributed to intramolecular crown ether catalysis, as neither anisole nor 2,6-dimethylanisole furnish the corresponding phenol when subjected t o similar treatment.
99,2365 (1977). 119. R. E. Asay, J. S. Bradshaw, S. F. Nielsen, M. D. Thompson, 3. W. Snow, D. R. K. Masihdas, R. M. Izatt and J. J. Christensen, J. , 14, 85 (1977). 120. R. M. Izatt, J. D. Lamb, R. E. Asay, G. E. Maas, J. S. Bradshaw, J. J. Christensen and S. S. Moore,J. Amer. , 99, 6134 (1977). 121. G. E. Maas, J. S . Bradshaw, R. M. Izatt and J. J. Christensen, J Org. , 42, 3937 (1977). 122. J. S. Bradshaw and M. D. Thompson, J Org. , 43,2456 (1978). 123. K. : Vogtle, Tetrahedron Letters, 2573 (1977).