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5 Beautiful Mechanically Interlocked Molecular Machines and Switches . . . . . . 6 The Artwork of MIMs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Conclusions and Perspectives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
3 Crystal Structures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 The Transition to Cartoons . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 Technomorphism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 The Beauty of MIMs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
The V€ ogtle group was the first to prepare a pretzelane [143, 149] and has also applied a similar concept to rotaxanes: a [1]rotaxane [150] results when the ring of a [2]rotaxane is connected to its dumbbell; a “molecular 8” [151] a O b O HN O N H Cu O OMe O H N O O N N N + Cu Si O d H2 N O O O O O O O N F O O O O F F F FF F H2 N N Pd N N H2 O O O Pd N O O O O O N O c O N N Cu+ O N N + N N N OMe H N O N O S N O N H H N O O O O O O O O O S N O O F FF F F F F O N H2 N O N F O O O N O N O O Si O O F O O O F H2 N O O O O N F FF F N N F FF F N F F H2 N Pd N H2 O F O O O O Pd N H2 O e O O O O HN NH NH2+ O N N HN O f O O O NH2 NH O HN NH2+ O O NH N HN N O O O O O O N N O O NH2 NH O O O O O O F O O O O F N + Cu N N + Cu N N N O N N O O O O O O O O O O O Fig.