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7. H. Ogino, Bull. Chem. , 1977,50, 2459. 8. D. K . Cabbiness and D. W. Margerum, J. Am. Chem. ,1969, 91, 6540. 9. R. F. Ziola and M. Extine, Inorg. , 1981,20, 2709; R. F. Ziola, W. W. H. Gunther and J. M. Troup, J . Am. Chem. , 1981. 103,4629. 10. C. J. Pederson, J. Am. Chem. Soc.. 1970, 92, 386. For a fuller account on crown ethers see C. J. Pederson and H. K. Frensdorff, Angew. , Int. Ed. , 1972, 11, 16. 11. A. M. Sargeson, Chem. , 1979, 15, 23. 12. N. E. Dixon, W. G. Jackson, G. A. Lawrance and A.

1966,11, 1349; I. I. Chernyaev and T. D. , 1729; L. N. Essen, F. A. Zakharova and A. D. German, Zh. Neorg. , 1958,3,2654. 32. D. Geselowitz and H. Taube, in ‘Advances in Inorganic and Bioinorganic Mechanisms’, ed. A. G. Sykes, Academic, London, 1982, p. 391. 33. W. 3. Schaap, A. E. Messner and F. C. Schmidt, J. Am. Chem. ,1955,77,2683. 34. G . F. Reynolds, ‘Progress in Polarography’, Wiley, New York, 1962, p. 243. 35. J. D. Corbett, Acc. Chern. , 1981, 14, 239 and related papers. 36. R. Tsuchiya, A.

W. Gibbs and F. A. Genth, ‘Researcheson the Ammonia-Cobalt Bases’, Smithsonian Institution, Washington, 1856; reprinted in Am. J. , 1856, [Z] 23, 235, 248, 319; 1857, [2] 24, 86. 32. F. Claudet, philos. , 1851, 2, 253. 33. G. B. KauFfman, in ‘Dictionary of Scientific Biography’,ed. C. C. Gillispie, Charles Scribner’s Sons, New York, 1972, vol. 5, pp. 492-495. 34. G. B. Kauffman, J. Chem. , 1974,51, 522; ref. 5, pp. 69-70. 35. For discussions of some of these theories see F. Reitzenstein, Z. Anorg.

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