By Carroll Temple
Content material:
Chapter 1 Alkyl? or Aryl?Monosubstituted 1,2,4?Triazoles (pages 3–29):
Chapter 2 Alkyl? or Aryl?Disubstituted 1,2,4?Triazoles (pages 30–61):
Chapter three Alkyl? or Aryl?Trisubstituted 1,2,4?Triazoles (pages 62–95):
Chapter four 1,2,4?Triazolecarboxylic Acids and Their practical Derivatives (pages 96–120):
Chapter five Acyl?1,2,4?Triazoles (pages 121–129):
Chapter 6 Amino?1,2,4?Triazoles (pages 130–204):
Chapter 7 Diamino? and Triamino?1,2,4?Triazoles (pages 205–224):
Chapter eight Azido?, Azo?, Diazo?, Diazoamino (Triazeno?)?, Nitramino?, Nitrosamino?, and Nitro?1,2,4?Triazoles Containing a number of of those practical teams (pages 225–238):
Chapter nine O?Substituted Oxy?1,2,4?Triazoles (pages 239–250):
Chapter 10 S?Substituted Thio?, Sulfinyl?, or Sulfonyl?1,2,4?Triazoles, 3,3??Dithobis[1,2,4?Triazoles], and 1,2,4?Triazolesulfonic Acids and Their sensible Derivatives (pages 251–287):
Chapter eleven Mono?, Di?, and Trihalo?1,2,4?Triazoles (pages 288–296):
Chapter 12 1,2,4?Triazoles Containing multiple consultant functionality (pages 297–364):
Chapter thirteen Alkyl or Aryl?1,2,4?Triazolin?5?Ones (pages 365–403):
Chapter 14 Alkyl? or Aryl?1,2,4?Triazoline?5?Thiones (pages 404–442):
Chapter 15 1,2,4?Triazolin?5?Ones Containing multiple consultant functionality (pages 443–474):
Chapter sixteen 1,2,4?Triazoline?5?thiones Containing multiple consultant functionality (pages 475–502):
Chapter 17 Miscellaneous ?2(or ?1)?1,2,4?Triazolines Containing a number of consultant services (pages 503–515):
Chapter 18 1,2,4?Triazolidines (pages 516–525):
Chapter 19 1,2,4?Triazolidine?3,5?diones (pages 526–558):
Chapter 20 1,2,4?Triazolidin?3?one?5?thiones and 1,2,4?Triazolidine?3,5?dithiones (pages 559–566):
Chapter 21 Bi?, Di, Bis?, Tris?, and Poly(1,2,4?Triazoles, Triazolines, and Triazolidines) associated both at once or with Chain Containing Carbon (pages 567–598):
Chapter 22 1,2,4?Triazolium, Triazolinium, Triazolidinium, and Mesoionic Compounds (pages 599–658):
Chapter 23 Metal?triazole Complexes (pages 659–667):
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Additional info for Chemistry of Heterocyclic Compounds: Triazoles 1,2,4, Volume 37
Example text
7 9 186201. 81: 3 7 5 2 1 ~ 57: 3982a. 68: 29646e. 2. - I -methylS-(S-aminoirnidazol-l-yl)- 1 -benzyl1 -bcnzyl-3-phenyl-. 4-triazol-S-yl]- 51 l39906h 3927e 3SS96a 15916b. 6 8 29645d 29646e 4 6 1 1 147h, 47: 433Sc. 82: 156003g 8 5 4657Xc 73: P100073b 8 3 28165~ 83: 2816% 77: 71: 68 49: 57: 71: 77: 152071b PIJI80m 29646~ 11631a. 74: 355% 3982a. -methyl3-(aminomethyI)-4-benzyl3-(aminomethyl)-4-[3-(2-~hlorohcnzoyl)- 77: P164704y 3-(aminomethyl)-4-mcthyl- 62: 1647f 66:55438s 66: 108781,66:55438s 59: 2804c 62: 1647f 8 0 P133443v S-ethyl-2-thienyl]- 4-(3-amin0-2-naphthyI)-3-methyl4-(o-aminophenyl)-3-rnethyl- 3-(o-aminophenyl)-4-phenyl3-[(henzamido)methyl]-4-(4-~hlorophenyl)3-[(benzamido)methyl]-4-phenyl 4-(2-henzoyl-4-chlorophenyli-3-[[(henzyloxycarhonyl)amino]methyl]4-(2-benzoyl-4-chlorophenyl~-3-~chlorornethyl~- 4-(2-benroyl-4-chlorophenylI-3-ethyl4-(2-henzoyl-4-chlorophenyl)-3-[(formyloxy~me1hyl]4-(2-benzoyl-J-chlorophenyl)-3-(hydroxymethyt)4-(2-benzoyl-4-chlorophenyl)-3-(hydroxyme1hyI)-.
8 0 8284On X. 49: 13227a 12. 7 6 126882b 16. 64: 1945Xc 10. 64: 20HIc 24. 8 0 0hOX2d 28. 7 5 140792h 3 2 . 8 0 IS23hg 50 Alkyl- or Aryl-Disubstituted 1,2,4Triazoles 33. 6th 105162m 37. 62: 16232d 41. 6 0 : l l j S f 45. 73: 560381 49. 67:7357od 53. 6 8 6907Iv 57. 7 8 136179h 61. 76 X5193g 65. 70 84378a TABLE 2. 34. 38. 42. 46. 75: llX255p 72: 33572s 63: 1154la 7 4 I3l65lc 84: 90123d 54. 72: IOO864q 58. 73: 120582v 62. 77: 6191hq 66. 74 131811e SO. 35. 39. 43. 37. 51. 55. 59. 63. 76 99614g 36. 83: 188199n 57: 12470i 44.
3. ' Although the products are obtained in good yields, the formation of two types of by-products was observed. 3-7). 3-2, R = 2-CSH4N FlwlIo 559. ' These products were intermediates for the preparation of the corresponding 3-(aminomethy1)triazoles. 3-11, R = PhCH? 3-16 was isolated. 3-16 ] CH2CH2NEt2 I N (. 3-21. 3. 3-23 37 23-24 nervous system agents. These benzodiazepines are prepared from 442benzoylpheny1)triazole intermediates," and a number of reports have appeared on the preparation of the latter.